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Ball Milling Asymmetric Organocatalysis

The ability to conduct Nheterocyclic carbenecatalysed acyl anion chemistry under ballmilling conditions is reported for the first time. This process has been exemplified through applications to intermolecularbenzoin, intramolecularbenzoin, intermolecularStetter and intramolecularStetter reactions including asymmetric examples and demonstrates that this mode of.

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